\n \t \u4e3a\u4e86\u89e3\u51b3\u73af\u5883\u6c61\u67d3\u7684\u95ee\u9898\uff0c\u8fbe\u5230\u6e05\u6d01\u751f\u4ea7\u7684\u76ee\u7684\uff0c\u7b49\u79bb\u5b50\u4f53\u8868\u9762\u5904\u7406\u6280\u672f\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u6ce8\u610f\ufffd \ufffd\u7b49\u79bb\u5b50\u4f53\u662f\u6c14\u56fa\u6db2\u4e09\u6001\u4ee5\u5916\u7269\u8d28\u5b58\u5728\u7684\u53c8\u4e00\u79cd\u5e7f\u6cdb\u5b58\u5728\u7684\u57fa\u672c\u5f62\u6001\ufffd \ufffd\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\uff0c\u5982\u91c7\u53d6\u52a0\u70ed\uff0c\u5916\u52a0\u7535\u573a\u3001\u6fc0\u5149\u7167\u5c04\u7b49\u624b\u6bb5\uff0c\u4f7f\u5206\u5b50\u79bb\u89e3\u548c\u7535\u79bb\uff0c\u5f62\u6210\u81ea\u7531\u7535\u5b50\u548c\u79bb\u5b50\ufffd \ufffd\u5f53\u7535\u79bb\u4ea7\u751f\u7684\u5e26\u7535\u7c92\u5b50\u5bc6\u5ea6\u8fbe\u5230\u4e00\u5b9a\u7684\u6570\u503c\u65f6\uff0c\u7535\u79bb\u6c14\u4f53\u53d8\u6210\u7531\u5e26\u7535\u7c92\u5b50\u548c\u4e2d\u6027\u7c92\u5b50\u7ec4\u6210\u7684\u96c6\u5408\u4f53\uff0c\u6210\u4e3a\u7b49\u79bb\u5b50\u4f53\ufffd Plasma contains a variety of high-energy active particles such as various ions, excited molecules, free radicals and photons. The energy of the plasma can act on the material surface through the collision of radiation, neutral particle flow and ion flow, so that the material surface can be modified. sex \ufffd<\/p<\/p>\n
\n \t\u7b49\u79bb\u5b50\u4f53\u5185\u90e8\u7535\u5b50\u6e29\u5ea6\u5f88\u9ad8\uff0c\u800c\u6c14\u4f53\u7c92\u5b50(\u79bb\u5b50\u3001\u4e2d\u6027\u7c92\u5b50\u7b49)\u6e29\u5ea6\u5374\u53ef\u80fd\u5f88\u4f4e\uff0c\u8fd9\u79cd\u72b6\u6001\u7684\u7b49\u79bb\u5b50\u4f53\u79f0\u4e3a\u4f4e\u6e29\u7b49\u79bb\u5b50\u4f53\ufffd The use of low-temperature plasma to modify materials has the following outstanding advantages: it only modifies the surface of the material without damaging the material itself, and can retain the original physical and mechanical properties of the material to a large extent; plasma treatment can use various Gases, even gases that are not reactive in nature like inert gases, can also be used as reaction atmosphere; plasma treatment is a dry process, which only produces little pollution and toxic waste. Unlike traditional chemical treatment, which can cause problems such as solvent residues, it is A new energy-saving, water-saving and environmentally friendly new technology \ufffd<\/p<\/p>\n
\n \t\u5229\u7528\u6c1f\u78b3\u5316\u5408\u7269\u8fdb\u884c\u7b49\u79bb\u5b50\u4f53\u5904\u7406\uff0c\u5f15\u5165\u4e86\u542b\u6c1f\u57fa\u56e2\uff0c\u83b7\u5f97\u4f4e\u80fd\u8868\u9762\uff0c\u4ece\u800c\u4f7f\u6750\u6599\u83b7\u5f97\u5404\u79cd\u7279\u6b8a\u7684\u6027\u80fd\uff0c\u5e94\u7528\u4e8e\u5404\u4e2a\u65b9\u9762\uff0c\u662f\u6750\u6599\u6539\u6027\u7684\u4e00\u4e2a\u91cd\u8981\u624b\u6bb5\u3002<\/p>\n
\n <\/p<\/p>\n
\n 1. Application of fluorine-containing gas low-temperature plasma technology in the textile industry<\/p<\/p>\n
\n \t\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u4e0e\u7eba\u7ec7\u5370\u67d3\u4f01\u4e1a\u4f20\u7edf\u7684\u6e7f\u5904\u7406\u5de5\u827a\u6bd4\u8f83\uff0c\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u6280\u672f\u4f5c\u4e3a\u4e00\u79cd\u6709\u6548\u7684\u8868\u9762\u5904\u7406\u6280\u672f\uff0c\u662f\u4e00\u79cd\u6781\u5177\u53d1\u5c55\u524d\u9014\u7684\u6e05\u6d01\u751f\u4ea7\u6280\u672f\ufffd Research on the application of plasma processing technology in textiles at home and abroad mainly focuses on the following aspects: improving the spinning performance of wool fiber; improving the dyeing and printing performance of fiber; improving the anti-felting performance of wool; and the deepening effect of dyed fabrics. ; Improve the bonding force and interface strength between fiber and polymer matrix; enhance the pre-treatment effect of fabrics, etc. The atmosphere used is mostly oxygen, nitrogen, air, argon and other gases \ufffd<\/p<\/p>\n
\n \t\u5bf9\u7ec7\u7269\u8fdb\u884c\u8010\u4e45\u6027\u62d2\u6c34\u62d2\u6cb9\u591a\u529f\u80fd\u6574\u7406\uff0c\u56fd\u5185\u5916\u62a5\u9053\u8f83\u591a\u7684\u662f\u4ee5\u6709\u673a\u6c1f\u6811\u8102\u8fdb\u884c\u5904\u7406\u3002\u5229\u7528\u7b49\u79bb\u5b50\u4f53\u5904\u7406\uff0c\u5f15\u5165\u4e86\u542b\u6c1f\u57fa\u56e2\uff0c\u8fdb\u884c\u8010\u4e45\u6027\u62d2\u6c34\u62d2\u6cb9\u591a\u529f\u80fd\u6574\u7406\uff0c\u5728\u8fd9\u65b9\u9762\u7684\u7814\u7a76\u8fd8\u4e0d\u662f\u5f88\u591a\u3002<\/p>\n
\n \t\u4f7f\u7528\u542b\u6c1f\u6c14\u4f53\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u53ef\u4ee5\u63d0\u9ad8\u591a\u79cd\u7ea4\u7ef4\u7684\u62d2\u6c34\u62d2\u6cb9\u6027\u80fd\ufffd Yasuda used CF4 plasma to treat some common fiber fabrics such as polyester, nylon, vinylon, cotton, nylon, wool and silk. After treatment, the contact angle of the fabric increased to varying degrees, the surface tension decreased, and the fabric had good Water and oil repellency \ufffd\u6709\u4eba\u5229\u7528\u542b\u6c1f\u5355\u4f53\u5728\u68c9\u7ec7\u7269\u3001\u8148\u7eb6\u7ec7\u7269\u4e0a\u8fdb\u884c\u7b49\u79bb\u5b50\u4f53\u805a\u5408\uff0c\u4f7f\u7ec7\u7269\u83b7\u5f97\u826f\u597d\u7684\u9632\u6c34\u6548\u679c\ufffd \ufffd\u800c\u68c9\u7ec7\u7269\u7684\u67d4\u8f6f\u6027\u3001\u4fdd\u6c34\u7387\u3001\u989c\u8272\u53d8\u5316\u3001\u624b\u611f\u3001\u900f\u6c14\u6027\u7b49\u90fd\u4f18\u4e8e\u4f7f\u7528\u5546\u7528Scotchgad\u9632\u6c34\u9632\u6c61\u5242\u6d82\u5c42\u7684\u7ec7\u7269\ufffd \ufffd<\/p<\/p>\n
\n There are a variety of gases that can be used as plasma treatment atmosphere, including CF4, C2F4, C3F6, mixed gases of CF4 and H2, etc. These gases can improve the water-repellent properties of fabrics, and the water-repellent properties vary with the type of fluorocarbon used. Different, processing time and power size vary \ufffd\u91c7\u7528\u4e0d\u540c\u6c14\u4f53\u548c\u4e0d\u540c\u64cd\u4f5c\u6761\u4ef6\u5904\u7406\u4e0d\u540c\u7ec7\u7269\uff0c\u7ec7\u7269\u8868\u9762\u7684\u542b\u6c1f\u91cf\u6709\u660e\u663e\u4e0d\u540c\uff0c\u5f15\u5165\u7684\u542b\u6c1f\u57fa\u56e2\u4e5f\u6709\u6240\u4e0d\u540c\ufffd \ufffd\u91c7\u7528CF4\u4f5c\u4e3a\u6c14\u6c1b\u5904\u7406\u5c3c\u9f99\uff0c\u8868\u9762\u6c1f\u5143\u7d20\u542b\u91cf\u4e3a1-2%\uff1b\u4ee5C3F6\u4e3a\u6c14\u6c1b\uff0c\u8868\u9762\u6c1f\u5143\u7d20\u542b\u91cf\u4e3a2.3-7.8%\ufffd Through X-ray photoelectron spectroscopy (XPS), it was observed that CF4 plasma treatment produces fluorination on the fiber surface and introduces fluorine-containing groups. Analysis of the Cls spectrum shows that -C-O-C-, -CF, -CF2 and -CF3 groups increased, while -COH and -COOH groups decreased \ufffd\u5bf9\u4e0d\u540c\u7ec7\u7269\uff0c\u5f15\u5165\u7684\u4e3b\u8981\u57fa\u56e2\u4e5f\u6709\u4e0d\u540c\uff0c\u5bf9\u805a\u916f\u3001\u5c3c\u9f99\u3001\u7ef4\u5c3c\u7eb6\u548c\u68c9\u7ec7\u7269\u4e3b\u8981\u5f15\u5165-CF2\u57fa\u56e2\uff0c\u800c\u5929\u7136\u86cb\u767d\u8d28\u7ea4\u7ef4\u7f8a\u6bdb\u548c\u8695\u4e1d\u5219\u8868\u73b0\u4e3a\u5f3a-CF\u5438\u6536\ufffd \ufffd\u4e14C3F6\u5904\u7406\u6548\u679c\u4f18\u4e8eCF4\ufffd \ufffd<\/p<\/p>\n
\n \t\u5904\u7406\u6548\u679c\u7684\u8010\u4e45\u6027\u662f\u8bc4\u4ef7\u5904\u7406\u6548\u679c\u4f18\u52a3\u7684\u91cd\u8981\u6307\u6807\u4e4b\u4e00\ufffd Some people reported that fabrics after plasma treatment have a time effect, that is, the hydrophilic properties obtained will gradually decline after a period of time. However, polyester fabrics were treated with CF4 plasma and found that even if the treated materials were stored for 150 days, no F\/ There is a significant change in C, but there is no significant change in its water repellency. \ufffd\u7814\u7a76\u53d1\u73b0\u4f7f\u7528\u6c14\u4f53\u7684\u7ed3\u6784\u662f\u7ec7\u7269\u5904\u7406\u6548\u679c\u8010\u4e45\u6027\u7684\u91cd\u8981\u5f71\u54cd\u56e0\u7d20\ufffd \ufffd\u7ec7\u7269\u4f7f\u7528\u4e0d\u9971\u548c\u7ed3\u6784\u7684\u6c14\u4f53\u65f6\uff0c\u8010\u4e45\u6027\u8f83\u9971\u548c\u7ed3\u6784\u7684\u6c14\u4f53\u5dee\ufffd \ufffd\u539f\u56e0\u53ef\u80fd\u662f\u4e0d\u9971\u548c\u7ed3\u6784\u7684\u6c14\u4f53\u8fdb\u884c\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u65f6\u5bb9\u6613\u53d1\u751f\u805a\u5408\uff0c\u800c\u805a\u5408\u7269\u4e0e\u7ec7\u7269\u8868\u9762\u7ed3\u5408\u4e0d\u662f\u975e\u5e38\u7262\u56fa\ufffd \ufffd<\/p<\/p>\n
\n \t\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u540e\u83b7\u5f97\u7684\u62d2\u6c34\u6027\u7ecf\u8fc7\u6c34\u6d17\u548c\u70d8\u5e72\u5904\u7406It will weaken after washing, because the fluorine-containing groups on the fiber surface are prone to flipping after the fabric is washed, and the surface tension increases, causing the fabric’s water-repellent performance to decrease. High-temperature drying after washing will help restore the water-repellent performance. <\/p>\n
\n <\/p<\/p>\n
\n 2. Fluorine-containing monomer plasma treatment of other materials<\/p<\/p>\n
\n \t\u6da4\u7eb6\u8584\u819c(PET)\uff0c\u805a\u4e19\u70ef(PP)\u7b49\u662f\u73b0\u5728\u5e7f\u6cdb\u4f7f\u7528\u7684\u6750\u6599\ufffd \ufffd\u4f7f\u7528\u542b\u6c1f\u5355\u4f53\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u8fd9\u4e9b\u9ad8\u5206\u5b50\u6750\u6599\u53ef\u83b7\u5f97\u7279\u6b8a\u6027\u80fd\uff0c\u83b7\u5f97\u66f4\u5e7f\u6cdb\u7684\u7528\u9014\ufffd J.Piglowski et al. used C6F14 plasma to treat PET films and used them as biological treatment materials. After plasma treatment, the material did not cause any toxic reactions, did not affect its biocompatibility, and could improve its anticoagulation. performance \ufffd\u6709\u4eba\u62a5\u9053\u5728\u819c\u6750\u6599\u4e0a\u8fdb\u884c\u7b49\u79bb\u5b50\u4f53\u805a\u5408\uff0c\u5f97\u5230\u4e00\u5c42\u542b\u6c1f\u8584\u819c\uff0c\u53ef\u7528\u4e8e\u5206\u79bb\u6c27\u6c14\u548c\u6c2e\u6c14\ufffd \ufffd\u91c7\u7528C2F6\u548cH2\u6df7\u5408\u6c14\u4f53\u4e3a\u6c14\u6c1b\uff0c\u5f53\u6df7\u5408\u6c14\u4f53\u4e2dC2F6\u6bd4\u4f8b\u589e\u52a0\u65f6\uff0c\u6c27\u6c14\u7684\u6e17\u900f\u7cfb\u6570\u548c\u819c\u7684\u9009\u62e9\u6027\u90fd\u5f97\u5230\u63d0\u9ad8\ufffd The ink cartridge nozzle of a traditional inkjet printer has a coating containing polyimide, which is easily wetted by ink and affects the printing effect. Some people use fluorine-containing monomers as the atmosphere for plasma treatment to obtain water and oil repellency. surface, which improves the shortcomings of traditional ink cartridges and has applied for a number of patents. Using CF4\/CH4 plasma to treat the surface of the material can also obtain flame retardant properties. \ufffdXPS\u7814\u7a76\u8868\u660e\uff0c\u7ecf\u7532\u70f7\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u53ef\u5f97\u5230\u4e00\u5c42\u9ad8\u5ea6\u4ea4\u8054\u7684\u805a\u5408\u78b3\u819c\ufffd \ufffd\u7532\u70f7\u7b49\u79bb\u5b50\u4f53\u7684\u6c89\u79ef\u901f\u7387\u8d8a\u9ad8\uff0c\u805a\u5408\u819c\u7684\u539a\u5ea6\u6108\u539a\uff0c\u6108\u6709\u5229\u4e8e\u963b\u71c3\ufffd \ufffd\u65bd\u6765\u987a\u7684\u7814\u7a76\u4e5f\u8bc1\u5b9e\u805a\u4e19\u70ef\u819c\u7ecf\u7532\u70f7\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u540e\uff0c\u71c3\u70e7\u901f\u7387\u666e\u901a\u964d\u4f4e\uff0c\u7531\u6b64\u8bc1\u5b9e\u4e86\u9ad8\u5ea6\u4ea4\u8054\u4f5c\u7528\u7684\u78b3\u5c42\u5bf9\u7b49\u79bb\u5b50\u4f53\u6539\u6027\u805a\u5408\u819c\u7684\u8868\u9762\u6240\u8d77\u7684\u963b\u71c3\u4f5c\u7528\ufffd \ufffd<\/p<\/p>\n
\n \tSigurdurSigurdsson\u7b49\u4eba\u7528CF4\u7b49\u79bb\u5b50\u4f53\u5904\u7406PET\u548cPP\uff0c\u5904\u7406\u540e\u8868\u9762\u80fd\u964d\u4e3a2-20mJ\/m2\ufffd \ufffd\u6c34\u548c\u4e19\u916e\u6d17\u6da4\u5bf9\u5904\u7406\u540e\u8868\u9762\u7684\u758f\u6c34\u6027\u80fd\u5f71\u54cd\u4e0d\u5927\uff0c\u8bf4\u660e\u5904\u7406\u8868\u9762\u8f83\u4e3a\u7a33\u5b9a\ufffd \ufffdXPS\u8868\u660e\u758f\u6c34\u6027\u80fd\u968f\u7740\u8868\u9762\u4e0a\u975e\u6781\u6027\u57fa\u56e2-CF2-\uff0c-CF3\uff0c\u548c-CH2-CF2-\u7684\u589e\u52a0\u800c\u589e\u5927\ufffd Someone used CF4CH4\/CF4 plasma to modify the surface of PET, and found that different molar ratios of fluorocarbon mixed gases have different mechanisms of action, and divided them into three regions. Region 1 (0-83.3% CF4) is the plasma polymerization region, and region Plasma polymerization plays a major role in area 2 (83.3-96.2%CF4), etching plays a minor role, and etching and fluorinated grafting play a major role in area 3 (96.2-100%CF4). \ufffd<\/p<\/p>\n
\n <\/p<\/p>\n
\n 3. Conclusion<\/p<\/p>\n
\n \t\u7b49\u79bb\u5b50\u4f53\u6280\u672f\u80fd\u6e05\u6d01\u3001\u5feb\u901f\u3001\u9ad8\u6548\u7684\u6539\u53d8\u5404\u79cd\u6750\u6599\u7684\u8868\u9762\u6027\u80fd\uff0c\u5728\u7eba\u7ec7\u884c\u4e1a\u548c\u9ad8\u5206\u5b50\u6750\u6599\u9886\u57df\u5185\u6709\u7740\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\ufffd \ufffd\u4f7f\u7528\u4e0d\u540c\u7684\u6c1f\u78b3\u5316\u5408\u7269\u8fdb\u884c\u4f4e\u6e29\u7b49\u79bb\u5b50\u4f53\u5904\u7406\uff0c\u53ef\u4ee5\u83b7\u5f97\u7279\u6b8a\u7684\u4f4e\u80fd\u8868\u9762\uff0c\u7528\u4e8e\u5404\u79cd\u4e0d\u540c\u7684\u7528\u9014\ufffd \ufffd\u4f46\u76ee\u524d\u4f4e\u6e29\u7b49\u79bb\u5b50\u4f53\u6280\u672f\u5e94\u7528\u4e8e\u5de5\u4e1a\uff0c\u4ecd\u5b58\u5728\u5f88\u591a\u95ee\u9898\uff0c\u5982\u7b49\u79bb\u5b50\u4f53\u901a\u5e38\u5728\u771f\u7a7a\u4e2d\u4ea7\u751f\uff0c\u7ed9\u5927\u89c4\u6a21\u5e94\u7528\u5e26\u6765\u4e86\u56f0\u96be\ufffd \ufffd\u4e14\u6c1f\u78b3\u5316\u5408\u7269\u4f4e\u6e29\u7b49\u79bb\u5b50\u4f53\u8fdb\u884c\u8868\u9762\u6539\u6027\u7684\u53cd\u5e94\u673a\u7406\u5c1a\u672a\u660e\u786e\uff0c\u9650\u5236\u4e86\u5176\u8fdb\u4e00\u6b65\u5e94\u7528\ufffd \ufffd\u968f\u7740\u7b49\u79bb\u5b50\u4f53\u6280\u672f\u7684\u5b8c\u5584\uff0c\u5229\u7528\u7684\u6c1f\u78b3\u5316\u5408\u7269\u8fdb\u884c\u4f4e\u6e29\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u5c06\u5f97\u5230\u66f4\u5e7f\u6cdb\u7684\u5e94\u7528\ufffd <\/p>\n
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